For cations, the 3d fills first. Since this is an exercise in determining electronic configurations, no effort has been made to limit the possible species to observed ions. Thus, don't be surprised to see Na 3-. Be certain to follow Hund's rule and, for simplicity, fill the orbitals in partially filled subshells from left to right. Zn, Cd, Hg are called non typical transition element. Some exceptional electronic configuration of transition element are: Cr = 3d 5 4s 1, Nb = 4d 4 5s 1, Pb = 4d 10 5s 0, Ag = 4d 10 5s 1, Cu = 3d 10 4s 1, Mo = 4d 5 5s 1, Ru = 4d 7 5s 1, Pt = 5d 0 6s 1, Au = 5d 10 6s 1. These irregularities can be explain on the basis of half filled and full ...

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    The 3d subshell is completely filled in Arsenic. Now the 3s and 3p subshells get filled up with 2 and 6 electrons respectively, but after that instead of the 3d subshell, the 4s subshell gets filled up.(This is so because the 4s subshell has a lower energy level than 3d).So that makes it 20 electrons.

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    The chromium has 3d sub – shell which is partially – filled. So, one electron from 4s sub – shell gets promoted to 3d sub – shell. Now, this makes both 4s sub-shell and 3d sub-shell half-filled. This is the most stable electronic configuration of chromium.

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